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- W2348515449 abstract "Hexaglycidylcyclotriphosphazene(HGCP) was prepared from hexachlorocyclotriphosphzene and 2,3-epoxy-1-propanol.The products was structurally characterized by FT-IR,1H,31P,13C NMR spectroscopy and elemental analysis.The factors affecting the yield of HGCP,such as reagent,ratio of 2,3-epoxy-1-propanol /hexacholrocyclotriphosphazene(P),reaction temperature(T) and time(t) were investigated.The optimized process conditions were: 2,3-epoxy-1-propanol/hexacholrocyclotriphosphazene(P)=7.62,T=30 ℃ and t=4.0 h with tetrahydrofuran as solvent.The yield and purity of the resulting HGCP could be up to 78%.Results show that the HGCP exhibits prefect heat-resistance and flame retardant resistance,and the linear ablation rate of cross-linking products EPG-1 and EPG-2 could up to 0.344 mm/s and 0.364 mm/s,so it is suitable to be used as organic filler in insulation layer for the solid rocket motor." @default.
- W2348515449 created "2016-06-24" @default.
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- W2348515449 date "2012-01-01" @default.
- W2348515449 modified "2023-09-23" @default.
- W2348515449 title "Synthesis,characterization and thermal property of hexaglycidylcyclotriphosphazene(HGCP)" @default.
- W2348515449 hasPublicationYear "2012" @default.
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