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- W2348654073 abstract "The air-oxidization and diluted acid treatment were use to purify the single-walled carbon nanotubes (SWCNTs).It was found that oxidization in air atmosphere at 500 ℃ for 0.5 h led to an efficient elimination of the amorphous carbon impurities,metal catalyst particles at the tip of SWCNTs were disappeared by reflux in 1% nitric acid and 0.5 mol/L hydrochloric acid solution at 60 ℃ for 24 h.In the Grand Canonical Monte Carlo (GCMC) simulation,non-polar fluid molecule is modeled as a spherical Lennard-Jones,fluid molecule and carbon interactions are integrated over the whole nanotube.The adsorption isotherms of different pore widths are obtained by adjusting the parameter of pore size.Compared with experiment data of nitrogen adsorbed on SWCNTs at 77 K,based on the statistical integral equation,the average pore width of on SWCNTs is about 6 nm.The adsorption isotherms of hydrogen and methane on SWCNTs were predicted by the grand canonical Monte Carlo simulation.The capability of adsorption at 298 K and 0.1 MPa is,for hydrogen,0.015%,for methane,0.5%.The results showed that SWCNTs might be an effective coating material for solid phase micro-extraction." @default.
- W2348654073 created "2016-06-24" @default.
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- W2348654073 date "2010-01-01" @default.
- W2348654073 modified "2023-09-24" @default.
- W2348654073 title "Study on adsorption of single-walled carbon nanotubes coating for solid-phase microextraction" @default.
- W2348654073 hasPublicationYear "2010" @default.
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