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- W2348929622 abstract "By using the slip-casting technique, the formation of silicalite-1 seed layers on porous carbon support with 0.5 μm pore size and A12O3 supports with different pore sizes(0.1 μm and 4 μm) were studied. The effects of support property, seed size and solvent on the formation of seed layers were investigated in detail. The growth of silicalite-1 membranes on different seeded supports by hydrothermal synthesis was also evaluated. The SEM and XRD characterizations indicate that a continuous seed layer can be obtained on the smooth support with 0.1μm pore size by using any seed of 100 nm, 600 nm or 2.2 μm in size, whereas, on the coarse supports with either 0.5 μm or 4 μm pore size, a continuous seed layer can not be formed by using the above seed sizes and the same seeding time. At a longer contacting time, a seed layer can also be formed by using 100 nm seed on the supports with larger pore size, however, it is not uniform and smooth. For the hydrophobic carbon support, the ethanol seeding suspension , which has weak polarity, favors the formation of a continuous seed layer. The seed layers and membranes grown from the smaller seed are more uniform and continuous and possess smoother surfaces than those from larger seed. The seed layer and respective membrane formed from nanosized seed(100 nm) are the most uniform and compact. In this method of zeolite membrane synthesis by seed in twice, the quality of membrane mainly depends on the quality of the seed layer." @default.
- W2348929622 created "2016-06-24" @default.
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- W2348929622 date "2006-01-01" @default.
- W2348929622 modified "2023-09-28" @default.
- W2348929622 title "Factors Affecting the Formation of Zeolite Seed Layers on Different Porous Supports and Effects of Seed Layers on the Growth of Zeolite Membranes" @default.
- W2348929622 hasPublicationYear "2006" @default.
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