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- W2349091255 abstract "It has been found that the following differences exist between the two extractants, namely:1. The separation factors for every two adjacent rare earth elements (β_Z~(Z+1)) with P-215 as extractant are always larger than the corresponding values with P-204. As the acidity of the aqueous solution is changed, β_Z~(Z+1) (P-215) varies, while β_Z~(Z+1) (P-204) does not.2. If the extraction reaction is represented as:Ln~(n+)+(m/2)H_2A_2(?)LnA_n(m-n)HA+nH~+,the value of m for La P-215 is somewhat larger than that for Ce P-215, while the values of m for La P-204 and Ce P-204 are almost the same.3. Though the extraction constants for (La, Ce) P-204 are larger than that for (La, Ce) P-215, the nature of the alkyl group in the extractant molecule has a greater influence on La than on Ce.The above differences may be due to the extent of steric hindrance effect of the alkyl group and dehydration effect upon the establishing complexes of (La, Ce)P-215." @default.
- W2349091255 created "2016-06-24" @default.
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- W2349091255 date "1981-01-01" @default.
- W2349091255 modified "2023-09-25" @default.
- W2349091255 title "COMPARISON OF THE SOLVENT EXTRACTION PROPERTIES OF DI (2-ETHYLHEXYL) PHOSPHATE AND DI (1-METHYLHEPTYL) PHOSPHATE FOR RARE EARTH ELEMENTS" @default.
- W2349091255 hasPublicationYear "1981" @default.
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