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- W2349101481 abstract "The coupling of an equilibrated reaction with a membrane process is an alternative way to reach complete conversion of reactants. In this work, distillation of reactants coupling with selective pervaporation was used to remove water, a product of the esterification reactions of 1-butanol and acetic acid, to drive the reaction to completion. A model describing the kinetics of system was developed and the influences of different parameters such as the ratios of membrane area to volume of solution, the rate of distillation and the quantity of reflux were studied theoretically on the basis of the described model. Reaction rates contants were determined experimentally and composition of the solution was determined by a gas chromatograph, the experimental data validated the model's prediction in term of water concentrations. Appropriate activities were calculated using the UNIFAC group contribution method." @default.
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- W2349101481 date "2002-01-01" @default.
- W2349101481 modified "2023-10-08" @default.
- W2349101481 title "Kinetic model of pervaporation-distillation-esterification coupling process" @default.
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