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- W2349178001 abstract "Photo-differential scanning calorimetry(P-DSC) was used to characterize the photopolymerization kinetics for a mixture of 2-ethylhexyl acrylate(EHA),trimethylolpropane trimethacrylate(TMPTA) and nematic liquid crystal(LC,P0616A) with 2,4,6-trimethylbenzoyldiphenyl phosphine oxide(TPO) as photoiniator at different reaction temperatures(-40-80 ℃).The results revealed that photopolymerization is faster than the traditional free radical polymerizations,the conversion of the above mixture reaches the plateau in about 50 s,and there are maxima in photopolymerization rate and apparent kinetic constant.All final conversion and maximum photopolymerization rate(R_p,max) increase with the reaction temperature.When the reaction temperature rises to 20 ℃,the above values increase slightly.In addition,Rp,max decreases with increasing LC content,and the conversion increases slowly with increasing time.Noticeably,the final conversions for the above mixtures have littile difference at different LC contents,and all of them are closed to 80%.With increasing UV intensity,both Rp,max and the final conversion increase obviously,and the threshold value of UV intensity is 4 mW/cm2.However,Rp,max and the final conversion tend to decrease with increasing the average functionality of monomers." @default.
- W2349178001 created "2016-06-24" @default.
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- W2349178001 date "2011-01-01" @default.
- W2349178001 modified "2023-09-25" @default.
- W2349178001 title "Kinetics of Photopolymerization for the Acrylate/Liquid Crystal Mixture" @default.
- W2349178001 hasPublicationYear "2011" @default.
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