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- W2349206280 abstract "The electrodeposition reduction mechanism of Cr3+ in the system of citric acid aqueous solution was investigated by using steady polarization curve,cyclic voltammetry,chronopotentiometry,and AC impedance.The kinetic parameters and equation of Cr3+ electrodeposition were decided.The results show that the electrodeposition of Cr3+ is an electrochemistry determinative step,and the electrochemical reaction is finished in two steps.The first step is a rate determinative step and an irreversible process,in which Cr3+ obtains two electrons and is reduced to Cr+.The second step is a quasi-reversible process,in which Cr+ obtains one electron and is reduced to metal Cr.Cr3+ ion does not undergo prepositive chemical transformation reaction while it is reduced,but there are electrochemistry active middle products adsorbed on the cathodic surface.The apparent transfer coefficients of cathode and anode are 0.490 and 2.455,respectively.The chemical metric number of Cr3+ electrodeposition is 1,the order of reaction of cathode and anode is 1 and 0,respectively,and the apparent diffusion coefficient is 1.606×10-5 cm2/s." @default.
- W2349206280 created "2016-06-24" @default.
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- W2349206280 date "2008-01-01" @default.
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- W2349206280 title "Electrochemical deposition of trivalent chromium" @default.
- W2349206280 hasPublicationYear "2008" @default.
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