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- W2349411013 abstract "Calixarenes are cyclic oligomers obtained from the condensation of formaldehyde with phenols.They are regarded as the third-generation host molecules after the crown ether and cyclodextrin due to their intrinsic cage-like architectures.Besides,calixarenes can be used as an external electron donor to activate the ring-opening polymerization of e-caprolactone (CL) initiated by tris(2,6-di-tert-butyl-4-methylphenolate) lanthanides((Ln(OAr)_3)).The catalyst systems with the proper molar ratio of calix[6]arene and lanthanides had higher activities and get poly(e-caprolactone)(PCL) with higher molecular weight than Ln(OAr)_3 itself in the temperature of 0 ℃." @default.
- W2349411013 created "2016-06-24" @default.
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- W2349411013 date "2007-01-01" @default.
- W2349411013 modified "2023-09-26" @default.
- W2349411013 title "Activation of calix [6] arene in the ring-opening polymerization of ε-caprolactone catalyzed by rare earth aryloxide catalysts in low temperature." @default.
- W2349411013 hasPublicationYear "2007" @default.
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