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- W2349884313 abstract "Kinetics of coordinate reaction of asymmetric porphyrin-aminoamthraquinone compounds with cobalt(Ⅱ) in DMF has been studied spectrophotomertry in the presence of cadmium(Ⅱ) ion.The infuence of temperature and electron effect and steric hindrance of substituting group on apparent rate constants were discussed .The porphyrin molecules were calculated by using semiempirical PM3 method. Experimental data and theoretical discussion showed that degree of apparent rate constant depend on net charge at =N- atom and frontier orbital energy difference of porphyrin." @default.
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- W2349884313 date "2003-01-01" @default.
- W2349884313 modified "2023-09-23" @default.
- W2349884313 title "A study on the kinetics in the coordinate reaction of asymmetric porphyrin-aminoamthraquinone compounds with cobalt(II)" @default.
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