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- W2350386206 abstract "Abstract The continued development of novel drugs, proteins, and advanced materials strongly rely on our ability to self-assemble molecules in solids with the most suitable structure (polymorph) in order to exhibit desired functionalities. The search for new polymorphs remains a scientific challenge, that is at the core of crystal engineering and there has been a lack of effective solutions to this problem. Here we show that by crystallizing the polyaromatic hydrocarbon coronene in the presence of a magnetic field, a polymorph is formed in a β-herringbone structure instead of the ubiquitous γ-herringbone structure, with a decrease of 35° in the herringbone nearest neighbour angle. The β-herringbone polymorph is stable, preserves its structure under ambient conditions and as a result of the altered molecular packing of the crystals, exhibits significant changes to the optical and mechanical properties of the crystal." @default.
- W2350386206 created "2016-06-24" @default.
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- W2350386206 date "2016-05-10" @default.
- W2350386206 modified "2023-10-15" @default.
- W2350386206 title "An unforeseen polymorph of coronene by the application of magnetic fields during crystal growth" @default.
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- W2350386206 doi "https://doi.org/10.1038/ncomms11555" @default.
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