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- W2350512498 abstract "The standard enthalpy and standard entropy of liquid glycerol carbonate at 298.15K were calculated by the method of Benson group contribution,and the functional correlation between the heat capacity of the liquid glycerol carbonate and temperature was calculated by the method of Joback group contribution and Sternling-Brown equation.Based on the above thermodynamic data and those from literature,the thermodynamic data for glycerol carbonate synthesis from CO2 and glycerol,including reaction enthalpy,Gibbs free energy,standard equilibrium constant and reaction pressure were calculated.The results showed that the synthesis reaction was not feasible thermodynamically,and the coupling reaction was an effective method to promote the synthesis reaction." @default.
- W2350512498 created "2016-06-24" @default.
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- W2350512498 date "2010-01-01" @default.
- W2350512498 modified "2023-09-27" @default.
- W2350512498 title "Thermodynamic analysis on synthesis of glycerol carbonate from CO_2 and glycerol" @default.
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