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- W2350828687 abstract "A new porous crystal of [Cu(enMe)2]4 [H5VIV18O42(Cl)]8H2O constructed from metal-oxo cluster building blocks was hydrothermally synthesized and characterized by elemental analysis, IR, EPR and single-crystal X-ray diffraction. The compound crystallizes in tetragonal system, space group P4/nnc with a = 15.0034(3), c = 18.8149(3) ? V = 4235.27(14) ?, Z = 2, Dc = 2.055 g/cm3, Mr = 2620.74, m = 2.988 mm-1, F(000) = 2608, R = 0.0766, wR = 0.2118, S = 1.193, (Dr)max = 0.969×103 and (Dr)min = 0.454×103 e/3. The structure is a three-dimensional framework linked alternatively by [H5VIV18O42(Cl)]8- polyoxoanions and [Cu(enMe)2] complex cations." @default.
- W2350828687 created "2016-06-24" @default.
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- W2350828687 date "2003-01-01" @default.
- W2350828687 modified "2023-09-22" @default.
- W2350828687 title "[Cu(enMe)_2]_4[H_5V_(18)~(IV)O_(42)(Cl)]·8H_2O: Synthesis and Crystal Structure of Microporous Material Constructed from Metal-oxo Cluster Building Blocks and Metal Complex Fragments" @default.
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