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- W2350960784 abstract "Two synthetic strategies are investigated for the preparation of water-soluble iridium-based catalysts for NMR signal amplification by reversible exchange (SABRE). In one approach, PEGylation of a variant N-heterocyclic carbene provided a novel catalyst with excellent water solubility. However, while SABRE-active in ethanol solutions, the catalyst lost activity in >50% water. In a second approach, synthesis of a novel di-iridium complex precursor where the cyclooctadiene (COD) rings have been replaced by CODDA (1,2-dihydroxy-3,7-cyclooctadiene) leads to the creation of a catalyst [IrCl(CODDA)IMes] that can be dissolved and activated in water-enabling aqueous SABRE in a single step, without need for either an organic cosolvent or solvent removal followed by aqueous reconstitution. The potential utility of the CODDA catalyst for aqueous SABRE is demonstrated with the ∼(-)32-fold enhancement of 1H signals of pyridine in water with only 1 atm of parahydrogen." @default.
- W2350960784 created "2016-06-24" @default.
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- W2350960784 date "2016-05-26" @default.
- W2350960784 modified "2023-10-15" @default.
- W2350960784 title "Aqueous NMR Signal Enhancement by Reversible Exchange in a Single Step Using Water-Soluble Catalysts" @default.
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- W2350960784 doi "https://doi.org/10.1021/acs.jpcc.6b04484" @default.
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