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- W2351680552 abstract "Waterborne UV curable polyurethane acrylate(PUA)/epoxy acrylate(EA) hybrid emulsions were prepared by a phase inversion method, which uses waterborne PUA as the emulsifier and mixed with EA. FT-IR was applied to characterize the structure of the PUA resin and the hybrid emulsion before and after UV curing. Transmission electron microscopy(TEM) results show that the emulsion particles have an anomalous core-shell structure, which changes with EA contents. The effects of –COOH content, neutralization degree and EA content were also investigated. The results show that the emulsification performance of PUA is improved with the increase of –COOH content. However, it becomes stable when the content is above 2.3%. The maximum viscosity and electrical conductivity of the emulsion increase with the –COOH content. With the increase of neutralization degree, the particle size of the emulsion decreases and the stability improves and then becomes less stable. The viscosity of the system also increases with the increase of neutralization degree, but the water resistance decreases. Furthermore, the particle size and the flexibility of the cured film decrease with the increase of EA content, while the UV curing rate and hardness of the film increase when EA content increases. The water and heat resistance both increase and then decrease with the increase of EA content." @default.
- W2351680552 created "2016-06-24" @default.
- W2351680552 creator A5025540901 @default.
- W2351680552 date "2014-01-01" @default.
- W2351680552 modified "2023-09-23" @default.
- W2351680552 title "Preparation and Properties of UV Curable PUA/EA Core-Shell Emulsions" @default.
- W2351680552 hasPublicationYear "2014" @default.
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