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- W2352035466 abstract "In a supporting electrolyte of 0.2 mol·L-1 KH2PO4-K2HPO4(pH 6.80), a reduction peak of sparfloxacin(SPFX) with a potential of -1.40 V(vs Ag/AgCl) and adsorptive characteristics was observed by linear sweep voltammetry at Hg electrode. The adsorbed species are most probably the neutral molecules of SPFX. The saturated adsorption amount of 5.08×10-11 mol·cm-2 and an area occupied by each molecule of 3.27 nm2 at Hg electrode for SPFX were obtained. On the surface of the hanging mercury drop electrode, the adsorption obeys Langmuir adsorptiom isotherm. The adsorption coefficient β, the Gibbs energy of adsorption ΔGФ at 25 ℃, the number of electrons transferred n, the kinetic parameter of the irreversible system αnα and the rate constant of surface electrode reaction ks are 1.04×106, -34.33 kJ·mol-1, 2, 1.54 and 0.29 s-1, respectively. A method for the assay of SPFX was proposed by adsorptive stripping voltammetry. The detection limit of the method is 2.0×10-8 mol·L-1 under the optimized conditions." @default.
- W2352035466 created "2016-06-24" @default.
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- W2352035466 date "2002-01-01" @default.
- W2352035466 modified "2023-09-25" @default.
- W2352035466 title "Adsorptive Voltammetric Behavior of Sparfloxacin and Its Application" @default.
- W2352035466 hasPublicationYear "2002" @default.
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