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- W2352453760 abstract "To establish a capillary electrophoresis (CE) method for the separation of tryptophan enantiomers,chitosan,a cationic natural polymer,was employed as a chiral additive selector.The separation was performed in untreated fused-silica capillaries using a Model CL1030 capillary electrophoresis system.Chitosan solution,ca.0.01%~0.20% in 1% aqueous acetic acid was prepared as running buffer.As a complexing ion,Cu(Ⅱ) ion concentration in the buffer was varied from 1 mmol/L to 4 mmol/L.The effects of the concentration of chitosan and Cu2+,pH of the buffer were investigated.A best separation of tryptophan enantiomers was achieved by using 0.02% chitosan(by weight) and 2 mmol/L Cu2+ while the pH of the buffer was 3.5.The separation factor was 4.95 and the resolution was 1.6." @default.
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- W2352453760 date "2008-01-01" @default.
- W2352453760 modified "2023-09-23" @default.
- W2352453760 title "Enantioseparation of DL-tryptophan by Capillary Electrophoresis with Chitosan as Chiral Additive" @default.
- W2352453760 hasPublicationYear "2008" @default.
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