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- W2352578689 abstract "The alkaline isomerization of horse heart cytochrome c and ligand binding cyt c in the presence of pyridine and 2 methyl pyridine has been studied using cyclic voltammetry at a gold disc electrode modified with cysteine over a range of solution pH. At this modified electrode, cyt c shows a quasi reversible electrode process while the cyclic voltammograms of alkaline cyt c and py·cyt c only give cathodic peaks. At neutral pH, high concentrations (1.27 mol·L -1 ) of py and 2 mpy caused the formation of alkaline cyt c which appeared only when pH was above 9 in the absence of such ligands. These results confirm the conclusion of previous NMR studies that py and its derivatives induce the formationof the alkaline cyt c at neutral pH. Further investigation indicates that the inducement function is not involved in the ligand's coordination to the heme iron." @default.
- W2352578689 created "2016-06-24" @default.
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- W2352578689 date "2000-01-01" @default.
- W2352578689 modified "2023-09-23" @default.
- W2352578689 title "Electrochemical Study on the Alkaline Isomerization of Cytochrome c and Ligand Binding Cytochrome c in the Presence of Pyridine and 2- methyl- pyridine" @default.
- W2352578689 hasPublicationYear "2000" @default.
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