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- W2352837629 abstract "Comparative studies were carried out by using electrochemistry and in-situ FTIR spectroelectrochemistry for nonlinear optical complexes, S-benzyl-N-(ferrocenyl-1-methyl-metylidene)-dithiocarbazate nickel (II)/cobalt (II) complexes (Ni(LSB)2/Co (LSB)2). The results indicated that Ni(LSB)2 involves two consecutive reversible one-electron oxidation steps, while Co(LSB)2 involves only one two-electron oxidation step. Ni(LSB)2 complex that has a square planar configuration exhibits a moderately strong electronic communication between the two-ferrocene moieties, taking place through the skeleton chain of the ligand due to the extensive electron delocalization in the whole molecule and leads to the appearance of a strong nu c-c vibration band at 1,453 cm-1 during the oxidation process, while Co(LSB)2 complex that has a tetrahedral configuration shows low electron delocalization and has two almost identical ferrocene moieties." @default.
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- W2352837629 date "2003-02-01" @default.
- W2352837629 modified "2023-09-23" @default.
- W2352837629 title "[Study on S-benzyl-N-(ferrocenyl-1-methyl-metylidene)-dithiocarbazate nickel (II)/cobalt (II) complexes by in-situ FTIR spectroelectrochemistry]." @default.
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