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- W2352909184 abstract "With the help of the initial temperature(T0),at which DSC curves deviate from the basline,the onset temperature(Te) and maximum peak temperature(Tp) from the non-isothermal DSC curves at different heating rates(β),the thermal decomposition activation energy(EK and EO) and pre-exponential constant(AK) obtained by Kissinger′s method and Ozawa′s method,the value of be0(or p0) from Hu-Zhao-Gao′s equation and the value of ae0(0r p0) from Zhao-Hu-Gao′s equation,the values of specific heat capacity(Cp) obtained by microcalorimetry,density(ρ) and thermal conductivity(λ),the decomposition heat(Qd,taking half-explosion heat),Zhang-Hu-Xie-Li′s formula,Hu-Yang-Liang-Xie′s formula,Hu-Zhao-Gao′s formula,Zhao-Hu-Gao′s formula,thermodynamic relation formulae,Smith′s equation,Friedman′s formula,Bruckman-Guillet′s formula,Frank-Kamenetskii′s formula,Wang-Du′s formulas and Yoshida′s formulas,the values(T00,Te0 and Tp0) of T0,Te and Tp corresponding to β→0,thermodynamic parameters of activation reaction(ΔG≠、ΔH≠、ΔS≠),thermal explosion temperature(Tbe0 and Tbp0),adiabatic time-to-explosion(tTiad),50% drop height(H50) of impact sensitivity,critical temperature of hot-spot initiation(Tcr,hot-spot),critical ambient temperature of thermal explosion(Tacr),safety degree(Sd),thermal explosion probability(PTE),explosion potential(Ep) and shock sensitivity relative to m-dinitrobenzene(SS) of 1,1′-Dimethyl-5,5′-azotetrazole monohydrate(1,1′-DMATZ) and 2,2′-Dimethyl-5,5′-azotetrazole(2,2′-DMATZ) are calculated.The results show that(1) 1,1′-DMATZ is thermally stable;(2) the heat-resistance ability of 1,1′-DMATZ is better than that of 2,2′-DMATZ;(3) the different positions of the methyl group in the molecules are the principal factor affecting the thermal safety." @default.
- W2352909184 created "2016-06-24" @default.
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- W2352909184 date "2011-01-01" @default.
- W2352909184 modified "2023-09-23" @default.
- W2352909184 title "Thermal Safety of 1,1′-Dimethyl-5,5′-azotetrazole and 2,2′-Dimethyl-5,5′-azotetrazole" @default.
- W2352909184 hasPublicationYear "2011" @default.
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