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- W2353125064 abstract "The catalytic distillation process of the synthesis of dimethyl carbonate(DMC) by urea methanolysis method was investigated by the non-equilibrium model,and the interactions of the operating parameters of this process were analyzed to the actual operation by this model.The analysis results show that the reaction temperature is greatly affected by the heating effect of the rectifying and the reaction zone,while the temperature in the rectifying zone is not sensitive to the heating effect.The reaction temperature and the temperature in the rectifying zone is 180.0 ℃ and 136.0 ℃ and the DMC yield is 49.3% under the condition of 4∶1 of reflux ratio and the operating pressure of 1.0 MPa.The increase of the operating pressure is favorable for the DMC synthesis.The appropriate operation conditions are pressure 0.8-1.6 MPa,reaction temperature 180.0-185.0 ℃." @default.
- W2353125064 created "2016-06-24" @default.
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- W2353125064 date "2009-01-01" @default.
- W2353125064 modified "2023-09-26" @default.
- W2353125064 title "Modeling analysis for process operation of synthesis of dimethyl carbonate" @default.
- W2353125064 hasPublicationYear "2009" @default.
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