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- W2353376006 abstract "A magnesium-lanthanum mixed metal oxide was used as solid base for synthesis of 2,2-dimethylol-1-butanal from the reactions between formaldehyde and n-butyraldehyde for the first time.GC and GC-MS results showed that the main product was 2,2-dimethylol-1-butanal while 2-ethylacrylaldehyde was the principae by-product.Among the solid bases such as Mg-Al oxide,MgO and Mg-La oxide,the latter was found to be the optimal catalyst.Under proper conditions,i.e.,formaldehyde:butyraldehyde(molar ratio)=2.5∶ 1.0,after reaction for 4 h under 50 ℃,the conversion of butyraldehyde was 75% while the selectivity and the yield of 2,2-dimethylol-1-butanal were 37% and 28%,respectively.Furthermore,the catalyst could be easily separated from the reaction mixture and used repetitively for 4 times without significant loss of activity." @default.
- W2353376006 created "2016-06-24" @default.
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- W2353376006 date "2012-01-01" @default.
- W2353376006 modified "2023-09-26" @default.
- W2353376006 title "Magnesium-lanthanum mixed metal oxide:a solid base for synthesis of 2,2-dimethylol-1-butanal from formaldehyde and n-butyraldehyde" @default.
- W2353376006 hasPublicationYear "2012" @default.
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