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- W2353511533 abstract "Aggregation behaviors of two anionic azo polyelectrolytes with different chemical structures were studied in the tetraphydrofuran(THF)/water mixture.The aggregating process was traced by UV Vis absorption spectroscopy and the aggregates formed were imaged with transmission electron microscopy(TEM).The pH effect on the aggregation was also investigated.With the increasing of water content in THF/water mixture,the azo chromohpores in the polyelectrolytes aggregate gradually,which results in an obvious blue shift of the absorption maximum and a decrease of absorption intensity in the UV Vis spectra.In the solutions with high concentration of azo polyelectrolytes,the aggregates were visualized with TEM to be nano particles with average diameter of about 80?nm.Results shows that the aggregates are much more stable than the related aggragates formed form small azo functionalized amphiphile.In addition,due to the difference in the architecture style of zao chromophores and carboxyl groups,pH of the medium has an opposite effect on the PCAPE and PPAPE aggregates." @default.
- W2353511533 created "2016-06-24" @default.
- W2353511533 creator A5004142846 @default.
- W2353511533 date "2002-01-01" @default.
- W2353511533 modified "2023-09-23" @default.
- W2353511533 title "AGGREGATION AND MICELLE-LIKE NANO-STRUCTURE OF TWO AZO POLYELECTROLYTES" @default.
- W2353511533 hasPublicationYear "2002" @default.
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