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- W2353839476 abstract "The ZnS hollow nanospheres with holes were prepared by reacting ZnSO4 with H2S,the sulfide source,formed in the reaction of CS2 with ethylenediamine,1,3-propylenediamine,butylamine or 2-(2-Aminoethylamino)ethanol,which acted as template agent also,at 50 ℃ under agitating.The shape,particle size of about 100~850 nm and hole size of about 150~600 nm of ZnS hollow nanospheres with holes were shown by SEM and TEM images.These ZnS nanospheres with β cubic ZnS phase and composed by 2~5 nm of nanocrystals were proved by XRD and HRTEM.The blue shift of max in UV-vis displayed the effect of quantum size.The two aminos of amine template favor to act with Zn2+ form uniform and relatively smooth ZnS holey nanospheres,while hydroxyethyl took disadvantage.Reasonable mechanism of hole by H2S rushing out was suggested." @default.
- W2353839476 created "2016-06-24" @default.
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- W2353839476 date "2007-01-01" @default.
- W2353839476 modified "2023-09-26" @default.
- W2353839476 title "Synthesis of ZnS hollow nanospheres with different amine templates" @default.
- W2353839476 hasPublicationYear "2007" @default.
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