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- W2353885911 abstract "A star-shaped and hyperbranched polymer B–PE10P was synthesized by cationic ring-opening graft polymerization of dendritic hyperbranched polyester Boltorn TM H20 (B-OH) with glycidyl tertcarbonate (E10P). The influence of polymerization conditions on conversion rate of E10P monomer was studied. The optimal reaction conditions were determined as follows: molar ratio of E10P to ─OH equal to 30, molar ratio of BF 3 O(C 2 H 5 ) 2 to ─OH equal to 1.0, 7.5wt% dioxane as solvent, reaction temperature 40 °C, and reaction time 15 h. The synthesized star-shaped and hyperbranched polymer B–PE10P wascharacterized by FT-IR and 1 H-NMR. The average polymerization degree of B–PE10P branch and its number average molecular weigh were calculated as 22.1 and 8.2 × 10 4 , respectively." @default.
- W2353885911 created "2016-06-24" @default.
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- W2353885911 date "2012-01-01" @default.
- W2353885911 modified "2023-09-27" @default.
- W2353885911 title "Preparation of star-shaped and hyperbranched polyester modified acrylate resin and study on properties of its waterborne coating——Part I. Synthesis of star-shaped and hyperbranched polymer and its influencing factors" @default.
- W2353885911 hasPublicationYear "2012" @default.
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