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- W2353971107 abstract "n-Decane is a component of commonly used fuels, but so far studies into its pyrolysis mechanism are rare and the few existing mechanisms are inconvenient to use owing to their large scales. A small-scale chemical kinetic model (Mech33) for describing the process of n-decane pyrolysis containing 33 species and 75 elementary reactions was constructed. Based on partial equilibrium and quasi-steady state assumptions through sensitivity analysis, a smaller kinetic model (Mech22) containing 22 species and 59 reactions was developed from Mech33. Simulations of n-decane pyrolysis using these two models were compared with experimental data from flow reactor and shock tube over a wide range of temperatures and pressures. The results showed that Mech33 and Mech22 could reproduce the process of n-decane pyrolysis well and accurately predict the concentrations profile of main products, and finally provide valuable chemical kinetic models for engineering simulations when coupled with computational fluid dynamics (CFD)." @default.
- W2353971107 created "2016-06-24" @default.
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- W2353971107 date "2013-01-01" @default.
- W2353971107 modified "2023-09-23" @default.
- W2353971107 title "Small-Scale Chemical Kinetic Mechanism Models for Pyrolysis of n-Decane" @default.
- W2353971107 hasPublicationYear "2013" @default.
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