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- W2354196559 abstract "Hexagonal WO3·0.33H2O and mixed WO3·0.33H2O(orthorhombic WO3·0.33H2O as the main phase) were synthesized by liquid method(80 ℃) and by ion-exchange and hydrothermal process(150 ℃),respectively,using Na2WO4·2H2O as the precursor.The samples were characterized by X-ray diffraction(XRD),Field Emission Scanning Electron Microscopy(FE-SEM),infrared spectra(FTIR),X-ray Photoelectron Spectroscopy(XPS) and Cyclic voltommetry.The inter-shifting of adjacent WO6 octahedron layers in orthorhombic WO3·0.33H2O produces voids,but ways appear in hexagonal WO3·0.33H2O for no displacement;Orthorhombic WO3·0.33H2O had shorter W=O and more minus conduction band than hexagonal WO3·0.33H2O.UV-Vis transmittance spectra indicate that more distinct electrochromism of hexagonal WO3·0.33H2O may be responsible for easy H+ diffusion into the structure and favorable to redox reaction.Photocatalytic property of mixed WO3·0.33H2O is better than hexagonal WO3·0.33H2O,because more minus conduction bands of orthorhombic WO3·0.33H2O are brought about due to easy absorption of electrons from valence band by electron acceptors and recombination restriction of electron-holes." @default.
- W2354196559 created "2016-06-24" @default.
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- W2354196559 date "2011-01-01" @default.
- W2354196559 modified "2023-09-25" @default.
- W2354196559 title "Structure and Properties of WO·_30.33H_2O Polymorphs" @default.
- W2354196559 hasPublicationYear "2011" @default.
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