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- W2354398475 abstract "The effect of Cl - ion on the anodic dissolution of iron in H 2SO 4 solutions containing low H 2S level has been stdied by electrochemical polarization curve measurements. Meanwhile, the stable adsorption patterns of Cl - and HS - ions on iron surface were determined with CNDO/2 method. Furthermore, the total energy and binding energy of the competitive adsorption between Cl - and HS -ions under the anodic potential as well as the net charge distribution of iron atoms were calculated. The results showed that certain concentration of Cl - ion could adsorb steadily in the anodic regions of electrode surface, reduce the interfacial concentration of HS - ion, and thereby inhibit the anodic reaction of iron. However, when Cl - ions reached saturated adsorption, the reaction courses changed into iron dissoltion promoted by Fe(Cl -) ads . The criticalconcentration of Cl - ion for the action transition was 1 mol/L." @default.
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- W2354398475 date "1999-01-01" @default.
- W2354398475 modified "2023-09-27" @default.
- W2354398475 title "EFFECT OF Cl~- ON ANODIC DISSOLUTION OF IRON IN H_2S-CONTAINING SULFURIC ACID SOLUTIONS" @default.
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