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- W2355016380 abstract "The reaction behavior of water in tetrahydrofuran polymerization initiated by a heteropolyacid,H 3PW 12 O 40 in the presence of ethylene oxide was studied.The variation of components during polymerization was monitored by gas chromatography.Most of water was converted in the earlier stage of the polymerization into ethylene glycol,which was consumed in the subsequent reaction process through chain transfer reaction.Water could not take part in the initiation reaction to start a polymer chain and might reduce the activity of the polymerization.Low molecular weight glycol such as ethylene or butylene glycol has a similar effect with water on controlling the molecular weight of the polymer.The molecular weight of the product can be predicted by an equation based upon concentrations of molecular weight controller and heteropolyacid,and conversion of polymerization." @default.
- W2355016380 created "2016-06-24" @default.
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- W2355016380 date "1999-01-01" @default.
- W2355016380 modified "2023-09-26" @default.
- W2355016380 title "THTRAHYDROFURAN POLYMERIZATION INITIATED WITH HETEROPOLYACID II.REACTION BEHAVIOR OF WATER" @default.
- W2355016380 hasPublicationYear "1999" @default.
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