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- W2355019318 abstract "Attempts to provide porous-layer open-tubular (PLOT) columns with Chromosorb 102, molecular sieve 5A, molecular sieve 13X and activated charcoal are described. The high separation performance of these PLOT columns at relatively high separation temperatures and shorter separation times is demonstrated by the example of the separation of low-boiling gases and isotope molecules. Precise measurements of the temperature dependence of separation factors and specific retention volumes supply the basis for the calculation of differences in the enthalpy and entropy of adsorption. A model of a molecular size isotope effect is proposed and validated experimentally." @default.
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- W2355019318 date "1969-01-01" @default.
- W2355019318 modified "2023-09-27" @default.
- W2355019318 title "The separation of nitrogen isotopes by gas chromatography" @default.
- W2355019318 cites W1978139561 @default.
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- W2355019318 doi "https://doi.org/10.1016/s0021-9673(01)97987-7" @default.
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