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- W2355907157 abstract "Penty (4′ propylcyclohexyl)triphenyl was synthesized by cross coupling reaction of 4 (4′ penty)biphenyl boronic acid and 1 bromo 4 trans (4′ propyl)cyclohexyl benzene catalyzed by PdCl 2 in the presence of cetrimonium bromide with coversion 93% and selectivity 86%. The structure of the product was confirmed by IR, 1H NMR and MS and it's phase temperature was determined by DSC. The influences of additive sequence and phase transfer catalysis are investigated. The catalytic mechanism cycle of the cross coupling reaction promoted by PTC is proposed, in which arylboronic acid takes part by the means of ion form ArB(OH) 3 -." @default.
- W2355907157 created "2016-06-24" @default.
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- W2355907157 date "2001-01-01" @default.
- W2355907157 modified "2023-09-23" @default.
- W2355907157 title "The Synthesis of 4-Pentyl(4′-propylcyclohexyl)tri-phenyl" @default.
- W2355907157 hasPublicationYear "2001" @default.
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