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- W2355947595 abstract "In Fe(SPh)~(-2)_4,the local environment around th e Fe~(2+)center ion is a trigonally distorted octahedron.In order to study t he zero-field splitting parameters of Fe(SPh)~(-2)_4,the crystal-field an d spin-orbit interaction complete diagonalizing Hamiltonian matrix of 3d~4/3d ~6 have been established by irreducible representation method.By using the EPR theory,the ground state energy levels and the zero-field splitting parameters(D,F-α) of Fe~(2+) ions in Fe(SPh)~(-2)_4 crystal are calculated by th e diagonalization of crystal-field and spin-orbit matrix.The calculated resul ts are in good agreement with the experimental data.It is confirmed that the sp ectrum construction of the material has Jahn-Teller effect." @default.
- W2355947595 created "2016-06-24" @default.
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- W2355947595 date "2006-01-01" @default.
- W2355947595 modified "2023-09-25" @default.
- W2355947595 title "Jahn-Teller Effect of Spectrum Construction and Zero-field Splitting Parameters in Fe(SPh)_4~(-2 )" @default.
- W2355947595 hasPublicationYear "2006" @default.
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