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- W2355985997 abstract "Ultra fine NiO/SiO2-TiO2 catalyst was prepared by sol-gel method.The reduced extrusion-shaped ultra fine NiO/SiO2-TiO2 catalyst had surface area of 350.5 m2·g-1,nickel content of 18.1wt% and bulk density of(0.70-0.75) g·cm-3.Kinetic behaviors of the catalyst for vapor-phase benzene hydrogenation was studied on a fixed bed micro-reactor.Assuming that benzene undergoes non-dissociative adsorption and hydrogen undergoes dissociative adsorption on the surface,and binding of the first hydrogen atom onto benzene is the determining step,an intrinsic kinetic equation was obtained which fit well with the experimental results,with average relative deviation of 6.88%.Rationality of the kinetic equation was verified by variance test and Boudart standard.Activation energy of the intrinsic reaction was obtained from the experimental data as 22.60 kJ·mol-1,lower than that of traditional commercial benzene hydrogenation catalysts." @default.
- W2355985997 created "2016-06-24" @default.
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- W2355985997 date "2007-01-01" @default.
- W2355985997 modified "2023-09-27" @default.
- W2355985997 title "Kinetic behaviors of ultra fine nickel-based NiO/SiO_2-TiO_2 catalyst for vapor-phase benzene hydrogenation" @default.
- W2355985997 hasPublicationYear "2007" @default.
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