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• W2356033133 abstract "By using DPC technique,we have systematically studied the photoinduced polymerization of ATMP in melted state and in solution state under different reaction conditions. The results show that the photoinduced polymerization of ATMP is greatly influenced by the reaction conditions such as the type and concentration of photoinitiator, reaction temperature, atmosphere as well as light intensity, and that the rate of photopolymerization of ATMP is directly proportional to the square root of photoinitiator concentration C0.5PI and incident light intensity I0.50, which is in accordance with he theoretical expectation. The kinetic parameters ( kp and kt) of the bulk photopolymerization of ATMP have been determined by photoDSC. The rate of propagation constant kp and the rate of termination constant kt increased with the increase of ATMP conversion, but kt is much larger than kp(kt/kp)= 100.01-394.78). By using EPR technique, we have monitored and estimated the concentration of the stable nitroxide radicals produced in situ during the photopolymerization of ATMP in the solution, and found that the content of the stable nitroxide radicals produced in the system is about the level of 10-7 mol/L, and that hadn't obviously influence on the rate and the conversion curves of ATMP photopolymerization." @default.
• W2356033133 created "2016-06-24" @default.
• W2356033133 creator A5059580136 @default.
• W2356033133 date "2003-01-01" @default.
• W2356033133 modified "2023-09-25" @default.
• W2356033133 title "Reactive-HALS III: Photopolymerization Kinetics of ATMP" @default.
• W2356033133 hasPublicationYear "2003" @default.
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