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• W2356323909 abstract "Prolinamide (2S,4R)-4-hydroxy-N-((S)-1-phenylethyl)pyrrolidine-2-carboxamide was found to be an efficient organocatalyst (10 mol %) for the direct asymmetric aldol reactions of isatins with acetone at −35 °C in THF and afforded the product in 79% yield with 74% ee. We have generalised the methodology for the direct asymmetric aldol reaction between isatin derivatives and acetone, and the corresponding aldol products were obtained in high yields (up to 99%) and with moderate enantioselectivities (up to 80%). This method has been applied to the enantioselective synthesis of (S)-convolutamydine." @default.
• W2356323909 created "2016-06-24" @default.
• W2356323909 creator A5018632619 @default.
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• W2356323909 date "2016-07-01" @default.
• W2356323909 modified "2023-10-12" @default.
• W2356323909 title "trans-4-Hydroxy-l-prolinamide as an efficient catalyst for direct asymmetric aldol reaction of acetone with isatins" @default.
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• W2356323909 doi "https://doi.org/10.1016/j.tetasy.2016.04.008" @default.
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