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- W2356511901 abstract "Cyclic sulfoxides derivative DTMSO is prepared by the alkylation of tetrahydrothiophene o oxide The capability and mechanism of extracting Pd 2+ with DTMSO is investigated The higher than 99%extraction rate is obtained with 0 3mol/L DTMSO in 1 0g/L Pd 2+ , 0 1mol/L HCl solution The efficiency becomes lower with low solvent concentration in high acidity solution, and it does not change with acidity for high solvent concentration This rapid reaction reaches equilibrium in 5 minutes The extraction rate of Pd 2+ falls as temperature increasing, and the color of solvent becomes deeper, puce appears at 60℃～70℃ Stripping rate reaches 87 5% with 5% Na 2SO 3 solution The results indicates that the reaction is neutral solvent complexing extraction and acid association extraction in lower acidity, the composition of extraction complex is (PdCl 2)·qDTMSO and ( H·qDTMSO) + PdCl 3 ,Pd is coordinated with O and S atom in S=O groups, the reaction is acid association extraction in higher acidity" @default.
- W2356511901 created "2016-06-24" @default.
- W2356511901 creator A5053330379 @default.
- W2356511901 date "2001-01-01" @default.
- W2356511901 modified "2023-09-26" @default.
- W2356511901 title "BEHAVIOUR OF EXTRACTING Pd WITH CYCLIC SULFOXIDE DERIVATIVE-DTMSO" @default.
- W2356511901 hasPublicationYear "2001" @default.
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