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- W2356553089 abstract "The hydrogen storage material of AlCl3 doped 4MgH2-Li3 AlH6 was successfully prepared by mechanical milling under an argon atmosphere.The effect of AlCl3 on the dehydrogenation of 4MgH2-Li3 AlH6 has been studied.The dehydrogenation performances of 4MgH2-Li3 AlH6-AlCl3 system were investigated by TG.The reaction mechanism was analyzed by XRD and DSC.The results show that AlCl3 as additive effectively increased the reaction activity of 4MgH2-Li3 AlH6,reduced the system dehydrogenation temperature and enhanced the dehydrogenate capacity.When 4mol% AlCl3 was doped into 4MgH2-Li3 AlH6,initial dehydrogenation temperature of this system was about 130℃ which was lower 43℃than 4MgH2-Li3 AlH6 ′s,and the total amount of dehydrogenation increased from 5.5wt% to 6.3wt%(up to 400 ℃).Meantime,the study on the mechanism of dehydrogenation for 4MgH2-Li3 AlH6-AlCl3 system shows that a part of Li3 AlH6 reacted with AlCl3 during ball-milled and activity Al was produced in situ.The activity Al helped to improve dehydrogenation performances of the system." @default.
- W2356553089 created "2016-06-24" @default.
- W2356553089 creator A5058644511 @default.
- W2356553089 date "2013-01-01" @default.
- W2356553089 modified "2023-09-28" @default.
- W2356553089 title "Effect of AlCl_3 on the Dehydrogenation of 4MgH_2-Li_3AlH_6" @default.
- W2356553089 hasPublicationYear "2013" @default.
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