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- W2356565303 abstract "Emfs for the cell without liquid junction:Pt, H-2(101.325kPa) Li2B4O7 (m(1)), CaCl2 (m(2)) AgCl - Ag are reported at five temperatures from 278.15 to 318.15 It. The standard association constant of ionic pair [CaB(OH)(4)](+), K-d is determined by fitting to the cell results. The dependence of pK(d) on temperature T is expressed by an empirical equation: pk(d) = 0.6857 - 359.72/ T - 4.632 x 10(-3) T. The other thermodynamic quantities of the association process are also calculated. The results show that the driving force for the ion association reaction is association entropy. Emfs for the cell without liquid junction:Pt, H-2(101.325kPa) Li2B4O7 (m(1)), CaCl2 (m(2)) AgCl - Ag are reported at five temperatures from 278.15 to 318.15 It. The standard association constant of ionic pair [CaB(OH)(4)](+), K-d is determined by fitting to the cell results. The dependence of pK(d) on temperature T is expressed by an empirical equation: pk(d) = 0.6857 - 359.72/ T - 4.632 x 10(-3) T. The other thermodynamic quantities of the association process are also calculated. The results show that the driving force for the ion association reaction is association entropy." @default.
- W2356565303 created "2016-06-24" @default.
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- W2356565303 date "1999-01-01" @default.
- W2356565303 modified "2023-09-23" @default.
- W2356565303 title "The thermodynamics of aqueous borate solutions 4. The standardassociation constant of ion pair [CaB(OH)(4)](+)" @default.
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