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- W2357181796 abstract "Reaction of CoCl2·6H2O,4-amino-3,5-di(2-pyridyl)-4H-1,2,4-triazole(abpt),KSCN results in formation of two new complexes,0D mononuclear complex named [CoSCN(abpt)](1α) and 2D inorganic coordination framework K2[Co3(OH)2(SO4)3(H2O)2](1β),in the same hydrothermal reaction system and were characterized by elemental analysis and IR.X-ray diffraction crystal structure analysis shows that 1α crystallizes in monoclinic system,space group P21/c with a=1.073 91(11) nm,b=1.589 59(16) nm,c=1.740 41(18) nm,β=106.720(2)°,V=2.845 4(5) nm3,Z=4;and 1β crystallizes in orthorhombic system,space group Cmc21 with a=1.794 24(17) nm,b=0.755 83(7) nm,c=0.976 05(10) nm,V=1.323 7(2) nm3,Z=4.In complex 1α,both abpt and SCN-ligands are coordinated to Co(Ⅱ) to form two different mononuclear units and further generate a 3D supramolecular architecture by the hydrogen bonds between the S atoms and uncoordinated N atoms of the abpt ligand.While in 1β,the abpt ligand is uncoordinated and the SCN-anion is changed to SO42-anion coordinated to Co(Ⅱ) atoms to result in a 2D coordination layer.Adjacent layers are linked to each other by hydrogen bonds to generate a 3D porous supramolecular architecture with 1D channels running along the c-axis,which are occupied by the counter K+ ions.CCDC: 658233,1α;CSD: 418495,1β." @default.
- W2357181796 created "2016-06-24" @default.
- W2357181796 creator A5075198995 @default.
- W2357181796 date "2007-01-01" @default.
- W2357181796 modified "2023-09-25" @default.
- W2357181796 title "Hydrothermal Synthesis and Crystal Structure of 2D K_2[Co_3(OH)_2(SO_4)_3(H_2O)_2] Coordination Polymer with the In-Situ Formation of SO_4~(2-)" @default.
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