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- W2357488306 abstract "Inverse gas chromatography(IGC)is a fast and reliable technique to measure the solventpolymer interplay.In this study,the infinite dilute activity coefficients and infinite dilute diffusioncoefficients of n-heptane,thiophene,2-methylthiophene,2,5-dimethylphene and ethyl sulfide in poly[bis(trifluoroethoxy)phosphazene](PTFEP)were determined in the temperature ranging from 353.15Kto373.15 K with an increment of 5K.The infinite dilute selectivites were measured from the experimental data,the pre-exponential factors and activation energy were also obtained according to Arrhenius equation.The experiment results showed that higher temperatures would accelerate the diffusion rate and also increase the sorption on membrane surface.And the diffusion through the membranes was affected by sizes of solvent molecules and the interactions between solvents and polymer.The obtained data would contribute to the study of transferring mechanism in PTFEP membranes." @default.
- W2357488306 created "2016-06-24" @default.
- W2357488306 creator A5023984232 @default.
- W2357488306 date "2015-01-01" @default.
- W2357488306 modified "2023-09-26" @default.
- W2357488306 title "Infinite dilute activity coefficients and diffusion coefficients of organics in PTFEP by inverse gas chromatography" @default.
- W2357488306 hasPublicationYear "2015" @default.
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