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- W2357999906 abstract "Objective To study the thermodynamic properties of disulfiram-hydroxypropyl-β-cyclodextrin(DSF-β-CD_(HP)) inclusion complexes and determine the equilibrium constants of the inclusion complex.Methods The reverse-phase high performance liquid chromatogram was employed to determine the retention times of DSF-β-CD_(HP) under different conditions,then the equilibrium constants and thermodynamic parameters were calculated.Results The inclusion complexes containing equimolar disulfiram(DSF) and hydroxypropyl-β-cyclodextrin(β-CD_(HP)) were formed when the concentration of β-CD_(HP) was low.The equilibrium constant of inclusion complexes was confirmed to be 1 624.41 L·mol~(-1) at 30 ℃ through the way of RP-HPLC.The changes of enthalpy(ΔH~0),Gibbs' free energy(ΔG~0) and entropy(ΔS~0) of the system during the formation of DSFβ-CD_(HP) were-25.25 kJ·mol~(-1),(-12.60 kJ·mol~(-1)) and41.74 J·mol~(-1)K~(-1) respectively.Conclusions The negative free energy change of this reaction demonstrate the spontaneous formation of DSF-β-CD_(HP),which caused by the intermolecular hydrogen bond and Van der Waals forces.The low temperature is useful for the formation of inclusion complexes." @default.
- W2357999906 created "2016-06-24" @default.
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- W2357999906 date "2006-01-01" @default.
- W2357999906 modified "2023-09-23" @default.
- W2357999906 title "Studies on equilibrium constants of DSF-β-CD_(HP) inclusion complexes and thermodynamic properties" @default.
- W2357999906 hasPublicationYear "2006" @default.
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