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- W2358901670 abstract "A series of Abs and α-MAbs graft copolymers with different acrylonitrile(AN) contents were synthesized by graft co-polymerizing styrene(St) and α-methyl styrene(α-MSt) and acrylonitrile(AN) monomer mixture onto polybutadiene(PB) latex rubber particles with seed-emulsion polymerization technique.By melt blending these copolymers with PVC resin,PVC/Abs blends were prepared.The miscibility and morphology of the blends were investigated by using TEM,SEM and Dynamic mechanical analysis(DMA).It was found that all PVC/Abs blends are immiscible for SAN copolymer with different AN content.When AN contents were 18.7%~23.6% in α-MSAN copolymer,a single tanδ Peak over room temperature in DMA detection was found.PVC/α-MAbs blends became miscible system because of the introduction of α-MSt into the SAN copolymer.When AN content was 32.1% in α-MSAN copolymer,the PVC/α-MAbs blends became partly miscible system.The morphology result showed that the phase domain size of the PVC/Abs blends intensively depend on AN content of SAN copolymer in Abs graft copolymer,and it agree well with the results of dynamic mechanical analysis." @default.
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- W2358901670 date "2010-01-01" @default.
- W2358901670 modified "2023-09-25" @default.
- W2358901670 title "Investigation of miscibility and morphology of PVC/Abs blends" @default.
- W2358901670 hasPublicationYear "2010" @default.
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