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- W2358982895 abstract "CuO/ZnO/Al2O3(CZA) and Zr-CuO/ZnO/Al2O3(Zr-CZA) catalysts were prepared by parallel current co-precipitation method,and characterized by XRD,FT-IR,SEM and BET.The performances of the catalysts for synthesis of methanol from syngas/CO2 were investigated in a slurry reactor.Results showed that?the specific surface area of catalyst Zr-CZA was up to 176.19m2·g-1,much higher than that of catalyst CZA(89.11m2·g-1);the isomorphous substitution reactions occurred in the precursors of both catalysts,generating active phase of rosasite and aurichalcite;XRD peaks of reduced Zr-CZA were more diffused,which indicated that its grain size of copper was smaller;and Zr-CZA obviously had higher CO conversion than CZA,and showed good stability in the life test of 566 h with a deactivation rate of only 0.103%/d." @default.
- W2358982895 created "2016-06-24" @default.
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- W2358982895 date "2015-01-01" @default.
- W2358982895 modified "2023-09-24" @default.
- W2358982895 title "Effect of Zr on performance of CuO/ZnO/Al_2O_3 catalyst for synthesis of methanol from syngas/CO_2 in a slurry reactor" @default.
- W2358982895 hasPublicationYear "2015" @default.
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