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- W2359572899 abstract "A alkaline earth metal-organic complex,namely,Sr(BuTA)0.5(H2O)2(1)(H4BuTA=1,2,3,4-Butanetetra-carboxylic acid),was obtained in water system by hydrothermal method based on flexible multi-carboxylate ligand.The title complex was characterized by elemental analysis and X-ray crystallography.The result of structural analysis shows that the complex 1 crystallizes in monoclinic,space group P21/c with a=0.870 03(5) nm,b=0.793 03(5) nm,c=1.268 07(5) nm,β=127.689(3)°,V=0.692 36(7) nm3,Z=4,Dc=2.290 g·cm-3,F(000)=468,μ=7.768 cm-1,the final R=0.015 8,wR=0.037 7.In complex 1,the coordination environment of Sr,is eight-coordinated with square antiprismatic geometry.The metal ions and ligands link each other to form a 3D framework of(46)2(412.612.84) topology,in which the BuTA2-anions act as rare 8-connected topological blocks.The thermal stability of complex 1 was also investigated." @default.
- W2359572899 created "2016-06-24" @default.
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- W2359572899 date "2011-01-01" @default.
- W2359572899 modified "2023-09-25" @default.
- W2359572899 title "Syntheses,Characterization,and Topological Analysis of an Alkaline Earth Metal-Organic Frameworks with Flexible Multi-Carboxylic ligand" @default.
- W2359572899 hasPublicationYear "2011" @default.
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