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- W2359794617 abstract "A type nano-SiO2/polyurethane-fluorinated acrylate(SiO2/FPUA)hybrid emulsion was synthesized by seeded emulsion polymerization using polyurethane(PU)as seed,which served as shell phase in the hybrid emulsion mentioned above,with the core phase consisting of nano-SiO2 modified by γ-(methacryloxy)propyltrimethoxy silane(KH-570),methyl methacrylate(MMA),butyl acrylate(BA)and dodecafluoroheptyl methacrylate(DFMA).The influence of the amount of nano-SiO2 and fluorine-containing monomer(DFMA)on emulsion polymerization process and surface hydrophobic properties of the latex films were discussed.The nano-SiO2/fluorinated polyacrylate emulsion and the latex film were characterized by Fourier transform infrared spectrum(FT-IR),transmission electron microscopy(TEM),contact angle(CA),thermogravimetry(TG),differential scanning calorimetry(DSC)and mechanical properties test(MPT)analysis.The results indicated that the latex particles showed a reverse core-shell structure,with PA as core and PU as shell,and the hydrophobicity and comprehensive properties of the latex film were greatly improved owing to the synergistic effect of DFMA and nano-SiO2." @default.
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- W2359794617 date "2012-01-01" @default.
- W2359794617 modified "2023-09-26" @default.
- W2359794617 title "Synthesis and characterization of nano-SiO_2/polyurethane-fluorinated polyacrylate hybrid emulsion" @default.
- W2359794617 hasPublicationYear "2012" @default.
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