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- W2359806365 abstract "Two organic hybrid tellurite 髧 sulfide compound(H2en)TeS3(1) and [Ni(en)3]TeS3(2)(en =ethylenediamine) were Solvothermally synthesized and structurally characterized by elemental analysis, singlecrystal and powder X-ray diffraction, IR, TGA and UV-Vis diffuse reflectance spectroscopy. Compound 1 and 2crystallizes in the monoclinic space group P21 and P21/c. Both composed of the discrete trigonal-pyramidal [TeS3]2-anion with complex cations [H2en]2+or [Ni(en)3]2+as counterions. In the compound 1, the bio-protonated amine of[H2en]2+and [TeS3]2-are connected by N-H…S hydrogen bonds. In the compound 2, the Ni2+is octahedral coordination geometry coordinated by six N atoms from three ethylenediamine ligands. CCDC: 927921, 1; 927922,2." @default.
- W2359806365 created "2016-06-24" @default.
- W2359806365 creator A5010179639 @default.
- W2359806365 date "2014-01-01" @default.
- W2359806365 modified "2023-09-23" @default.
- W2359806365 title "Solvothermal Synthesis and Characterization of Two Thio-Tellurite(H_2en)TeS_3 and [Ni(en)_3]TeS_3" @default.
- W2359806365 hasPublicationYear "2014" @default.
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