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- W2359879264 abstract "The catalysts for selective oxidation of propene to acrolein were prepared by coprecipitation method.The effects of organic amine addition on the performance of the catalysts for propene selective oxidation to acrolein were investigated.The results showed that with the addition of organic amine,the activity of the catalyst was stable whereas the selectivity was enhanced greatly.The catalysts were characterized by means of scanning electron microscope,X-ray diffraction,pyridine adsorbed infrared spectrum and N2physisorption techniques.The results showed that though the surface area of the catalyst decreased slightly,the amount of L-acid sites on the catalyst surface increased obviously,which had little influence on the catalyst activity.On the other hand,the decrease of MoO3 crystallinity and the increase of(Co0.7Fe0.3)(MoO4) crystallinity were positive factors to the selectivity of the catalyst.Meanwhile,the decreased pore volume and the increased ratio of large pores of the catalyst were attributed to the faster removal of the products from the catalyst surface and the inhibition of the formation of deep oxides." @default.
- W2359879264 created "2016-06-24" @default.
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- W2359879264 date "2013-01-01" @default.
- W2359879264 modified "2023-09-24" @default.
- W2359879264 title "Effects of additive organic amine on the activity of the catalyst for selective oxidation of propene to acrolein" @default.
- W2359879264 hasPublicationYear "2013" @default.
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