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- W2359883383 abstract "To adjust structures and improve properties of rubber,polybutadiene(PB)/allyllsobutyl polyhedral oligomeric silsesquioxane(POSS)nanohybrids were successfully synthesized by anionic polymerization with n-BuLi as a initiator,cyclohexane as a solvent,tetrahydrofufuryethylether(ETE) as a polar modifier.The effects of reaction conditions,content of polar modifies ETE and POSS on the copolymerization of butadiene/POSS and microstructure of the nanohybrids were investigated.Results show that the addition of POSS obviously decreases the copolymerization rate and molecular weight,meanwhile,the molecular weight distribution(MWD) increases.The reaction conditions have limited effects on the copolymerization.However,the incorporation of POSS significantly increases the copolymerization speed and the 1,2-structure contents in PB and POSS,which show good cooperation with polar modifier ETE on adjusting structure of PB." @default.
- W2359883383 created "2016-06-24" @default.
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- W2359883383 date "2009-01-01" @default.
- W2359883383 modified "2023-09-23" @default.
- W2359883383 title "Preparation of polybutadiene nanohybrid containing allyllsobutyl polyhedral oligomeric silsesquioxane by anionic polymerization and its microstructure" @default.
- W2359883383 hasPublicationYear "2009" @default.
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