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- W2359901761 abstract "Some framework materials show unique properties due to their special atomic arrangement,among them some show negative thermal expansion,for example Zr W2O8,Zr Mo2O8,et al,zeolite and Prussian blue analogues show negative thermal expansion( volume contracts with increasing temperature). Recently,researches about metal-organic frameworks based on coordination chemistry developed rapidly, numerous structures have been found. Some metal-organic frameworks( MOFs) show abnormal thermal expansion,for example,IRMOFs,HKUST-1,MIL-53 show negative thermal expansion,while some MOFs show colossal thermal expansion,such as Ag3Co( CN)6. Most framework materials show negative thermal expansion due to the transverse vibration of the bridging atoms,while,as for MOFs,the flexibility and the rotation of ligands also contribute to thermal expansion properties. This paper is mainly concerning abnormal thermal expansion properties of MOFs to inspire more researchers' interest." @default.
- W2359901761 created "2016-06-24" @default.
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- W2359901761 date "2015-01-01" @default.
- W2359901761 modified "2023-09-27" @default.
- W2359901761 title "Abnormal Thermal Expansion in Metal- Organic Frameworks" @default.
- W2359901761 hasPublicationYear "2015" @default.
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