Matches in SemOpenAlex for { <https://semopenalex.org/work/W2360434961> ?p ?o ?g. }
- W2360434961 endingPage "71" @default.
- W2360434961 startingPage "66" @default.
- W2360434961 abstract "The thermodynamic properties of the liquid Ag–In alloys were determined using solid oxide galvanic cells with zirconia electrolyte. The e.m.f.'s of the cellsRe + kanthal, AgxIn(1−x),In2O3//ZrO2 + (Y2O3)//NiO, Ni, Ptwere measured in the temperature range from 950 to 1273 K, and in the molar fraction from xIn = 0.15 to 1.0. At first, the Gibbs free energy of formation of pure solid indium oxide, In2O3, from pure elements was derived. Using values of the e.m.f.'s measured for the cell with xIn = 1.0, the following temperature dependence was obtained:ΔfGm,In2O30(±1000mol−1J)=−911570+313.10TNext, the activities of indium were derived as a function of the alloy composition from measured e.m.f.'s. Activities of silver were calculated using Gibbs–Duhem equation. Also, using Darken's α-function formalism, activity coefficient of indium at infinite dilution in silver was calculated. These data taken together with the heat of mixing values which are available in the literature enabled the description of the thermodynamic properties of the liquid phase with Redlich–Kister polynomial expansion. Finally, the Ag–In phase diagram was recalculated using ThermoCalc software. The limiting value of the logarithm of the activity coefficient of indium in silver was also given as a function of temperature." @default.
- W2360434961 created "2016-06-24" @default.
- W2360434961 creator A5030572996 @default.
- W2360434961 creator A5068793480 @default.
- W2360434961 date "2005-08-01" @default.
- W2360434961 modified "2023-10-11" @default.
- W2360434961 title "Thermodynamic properties of liquid silver–indium alloys determined from e.m.f. measurements" @default.
- W2360434961 cites W1530757285 @default.
- W2360434961 cites W1972666114 @default.
- W2360434961 cites W1991410388 @default.
- W2360434961 cites W2012631812 @default.
- W2360434961 cites W2030693426 @default.
- W2360434961 cites W2031418343 @default.
- W2360434961 cites W2041675594 @default.
- W2360434961 cites W2063974699 @default.
- W2360434961 cites W2073394336 @default.
- W2360434961 cites W2096026520 @default.
- W2360434961 cites W2106058250 @default.
- W2360434961 cites W2200360897 @default.
- W2360434961 cites W2319094505 @default.
- W2360434961 cites W2605761920 @default.
- W2360434961 cites W2607150318 @default.
- W2360434961 cites W2622593270 @default.
- W2360434961 cites W4253651073 @default.
- W2360434961 doi "https://doi.org/10.1016/j.tca.2005.02.005" @default.
- W2360434961 hasPublicationYear "2005" @default.
- W2360434961 type Work @default.
- W2360434961 sameAs 2360434961 @default.
- W2360434961 citedByCount "21" @default.
- W2360434961 countsByYear W23604349612012 @default.
- W2360434961 countsByYear W23604349612014 @default.
- W2360434961 countsByYear W23604349612016 @default.
- W2360434961 countsByYear W23604349612017 @default.
- W2360434961 countsByYear W23604349612018 @default.
- W2360434961 countsByYear W23604349612019 @default.
- W2360434961 countsByYear W23604349612020 @default.
- W2360434961 countsByYear W23604349612022 @default.
- W2360434961 crossrefType "journal-article" @default.
- W2360434961 hasAuthorship W2360434961A5030572996 @default.
- W2360434961 hasAuthorship W2360434961A5068793480 @default.
- W2360434961 hasConcept C113196181 @default.
- W2360434961 hasConcept C121332964 @default.
- W2360434961 hasConcept C146477669 @default.
- W2360434961 hasConcept C147789679 @default.
- W2360434961 hasConcept C170961132 @default.
- W2360434961 hasConcept C178790620 @default.
- W2360434961 hasConcept C184651966 @default.
- W2360434961 hasConcept C185592680 @default.
- W2360434961 hasConcept C191897082 @default.
- W2360434961 hasConcept C192562407 @default.
- W2360434961 hasConcept C2779851234 @default.
- W2360434961 hasConcept C2780026712 @default.
- W2360434961 hasConcept C29633239 @default.
- W2360434961 hasConcept C36591836 @default.
- W2360434961 hasConcept C39353612 @default.
- W2360434961 hasConcept C43617362 @default.
- W2360434961 hasConcept C44280652 @default.
- W2360434961 hasConcept C543292547 @default.
- W2360434961 hasConcept C85906118 @default.
- W2360434961 hasConcept C97355855 @default.
- W2360434961 hasConceptScore W2360434961C113196181 @default.
- W2360434961 hasConceptScore W2360434961C121332964 @default.
- W2360434961 hasConceptScore W2360434961C146477669 @default.
- W2360434961 hasConceptScore W2360434961C147789679 @default.
- W2360434961 hasConceptScore W2360434961C170961132 @default.
- W2360434961 hasConceptScore W2360434961C178790620 @default.
- W2360434961 hasConceptScore W2360434961C184651966 @default.
- W2360434961 hasConceptScore W2360434961C185592680 @default.
- W2360434961 hasConceptScore W2360434961C191897082 @default.
- W2360434961 hasConceptScore W2360434961C192562407 @default.
- W2360434961 hasConceptScore W2360434961C2779851234 @default.
- W2360434961 hasConceptScore W2360434961C2780026712 @default.
- W2360434961 hasConceptScore W2360434961C29633239 @default.
- W2360434961 hasConceptScore W2360434961C36591836 @default.
- W2360434961 hasConceptScore W2360434961C39353612 @default.
- W2360434961 hasConceptScore W2360434961C43617362 @default.
- W2360434961 hasConceptScore W2360434961C44280652 @default.
- W2360434961 hasConceptScore W2360434961C543292547 @default.
- W2360434961 hasConceptScore W2360434961C85906118 @default.
- W2360434961 hasConceptScore W2360434961C97355855 @default.
- W2360434961 hasIssue "1-2" @default.
- W2360434961 hasLocation W23604349611 @default.
- W2360434961 hasOpenAccess W2360434961 @default.
- W2360434961 hasPrimaryLocation W23604349611 @default.
- W2360434961 hasRelatedWork W1745925828 @default.
- W2360434961 hasRelatedWork W2001709140 @default.
- W2360434961 hasRelatedWork W2035490332 @default.
- W2360434961 hasRelatedWork W2116053002 @default.
- W2360434961 hasRelatedWork W2124477330 @default.
- W2360434961 hasRelatedWork W2360434961 @default.
- W2360434961 hasRelatedWork W2518316022 @default.
- W2360434961 hasRelatedWork W2620961526 @default.
- W2360434961 hasRelatedWork W4247858605 @default.
- W2360434961 hasRelatedWork W4313404156 @default.
- W2360434961 hasVolume "433" @default.
- W2360434961 isParatext "false" @default.
- W2360434961 isRetracted "false" @default.
- W2360434961 magId "2360434961" @default.