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- W2360438771 abstract "The copolymerization of CO2 and propylene oxide was performed using supported zinc glutarate catalyst,and the influence of additives,including trace water content,ethanol and propanal contents on the catalytic activity of supported zinc glutarate was exclusively investigated.Moreover,the composition and molecular structure of the resulting copolymers were studied accordingly.The experimental results demonstrate that the catalytic activity decreases obviously in the presence of trace ethanol and water.1H-NMR and 13C-NMR spectra reveal that the alternating copolymer is resulted,and the discussed additives show no effect on the carbonate linkage content in the copolymer.However,the all additives can decrease molecular weight and increase molecular weight distribution determined via GPC.Finally,with increasing impurities,the byproduct content,i.e.,propylene carbonate increases as indicated by GPC measurements." @default.
- W2360438771 created "2016-06-24" @default.
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- W2360438771 date "2007-01-01" @default.
- W2360438771 modified "2023-09-26" @default.
- W2360438771 title "Effect of Water,Ethanol and Propanal on the Copolymerization of Carbon Dioxide and Propylene Oxide" @default.
- W2360438771 hasPublicationYear "2007" @default.
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